Atomic Structure Chapter 2

35 MCQs

MCQs

35 questions · 35 min · 35 marks

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Sample questions

The first 5 of 35. Try each one, then tap to see the answer.

  1. Question 1

    The quantum number ‘m’ of a free gaseous atom is associated with:

    • AThe effective volume of the orbital
    • BThe shape of the orbital
    • CThe spatial orientation of the orbital
    • DThe energy of the orbital in the absence of a magnetic field
    Show answer

    Answer: C

    Section 2.4.3 states that the magnetic quantum number m describes the orientation of an orbital in space within a subshell.

  2. Question 2

    When the 3d subshell is completely filled, the next entering electron goes into:

    • A4f
    • B4s
    • C4p
    • D4d
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    Answer: C

    The textbook's stated increasing-energy order places 4p after 3d: 4s < 3d < 4p.

  3. Question 3

    Quantum number values for 2p orbitals are:

    • An = 2, l = 1
    • Bn = 1, l = 2
    • Cn = 1, l = 0
    • Dn = 2, l = 0
    Show answer

    Answer: A

    For a 2p orbital, the principal quantum number is n = 2 and the azimuthal quantum number for p is l = 1.

  4. Question 4

    An electron having the set of values n = 4, l = 0, m = 0 and s = +1/2 lies in:

    • A2s
    • B3s
    • C4s
    • D4p
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    Answer: C

    The textbook identifies l = 0 with an s subshell; n = 4 therefore indicates 4s, with m = 0 the only s-orbital orientation.

  5. Question 5

    The quantum number values (n, l, m) for the fourth electron of a Be atom (Z = 4) are:

    • A1, 0, 0
    • B2, 0, 0
    • C2, 1, 0
    • D1, 1, 1
    Show answer

    Answer: B

    The textbook gives beryllium's configuration as 1s²2s². Its fourth electron is in 2s, where n = 2, l = 0 and m = 0.

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